SR XRF and micro-PIXE studies on ancient metallurgy of thirteen Dacian gold bracelets

A thorough microscopic investigation by SR XRF and micro-PIXE brings insight into the probable techniques used in the manufacture of thirteen Dacian gold bracelets, one of the most spectacular archaeological finds ever on the territory of Romania.     

Barbilian’s metrization procedure in the plane yields either Riemannian or Lagrange generalized metrics

In the present paper we answer two questions raised by Barbilian in 1960. First, we study how far can the hypothesis of Barbilian’s metrization procedure can be relaxed. Then, we prove that Barbilian’s metrization procedure in the plane generates either Riemannian metrics or Lagrance generalized metrics not reducible to Finslerian or Langrangian metrics.     

The minimum degree distance of graphs of given order and size

In this note, we study the degree distance of a graph which is a degree analogue of the Wiener index. Given n and e, we determine the minimum degree distance of a connected graph of order n and size e.     

The kinetics of oxiranes addition to bis/2-hydroxyalkyl/disulfides and bis/2-hydroxyalkyl/sulfides in the presence of N,N-dimethylcyclohexylamine

Rate constants for the reaction of oxiranes with bis/2-hydroxyalkyl/disulfides, bis/2-Hydroxyalkyl/sulfides, and 1,6-Hexanediol in the presence of N,N-dimethylcyclohexylamine were studied at the temperature range of 50–90°C. A mechanism of these reactions has been proposed and its kinetic equation has been presented.     

Enantioselective organocatalytic α-sulfenylation of substituted diketopiperazines

The asymmetric organocatalytic α-sulfenylation of substituted piperazine-2,5-diones is reported, with cinchona alkaloids as chiral Lewis bases and electrophilic sulfur transfer reagents. Catalyst loadings, the type of sulfur transfer reagent, temperature, and solvent were investigated in order to optimize the reaction conditions. The effects of ring substitution and the type of catalyst on the yield and enantioselectivity of the reaction are reported.